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Atomic Structure and the Periodic Table

Isotopes and Relative Atomic Mass

AQA GCSE Chemistry


Mass number and the symbol

  • Mass number is the number of protons plus neutrons. Never write the mass of the protons and neutrons.
  • In a symbol, the mass number is at the top left and the atomic number is at the bottom left.
mass number 13 atomic number 6 C
The mass number and the atomic number written to the left of the symbol for carbon.

Protons, neutrons and electrons

ParticleNumber in an atom
Protonsthe atomic number
Neutronsthe mass number minus the atomic number
Electronsthe same as the number of protons

In an ion, the protons and neutrons are counted the same way. A positive ion has fewer electrons than protons, and a negative ion has more, by the size of its charge.

Isotopes

  • Isotopes are atoms of the same element with the same number of protons but different numbers of neutrons. Never write different relative atomic mass.
  • Isotopes of an element have different mass numbers because they have different numbers of neutrons.

Relative atomic mass

relative atomic mass = (mass number × percentage) for each isotope, added together100
Method: relative atomic mass from percentage abundances
  1. For each isotope, multiply its mass number by its percentage abundance.
  2. Add these together for every isotope.
  3. Divide the total by 100, and write down the value in full.
  4. Round it to the number of decimal places or significant figures asked for.
  • Relative atomic mass lies closer to the mass number of the more abundant isotope.
  • A relative atomic mass exactly halfway between the mass numbers of two isotopes means there are the same number of atoms of each isotope.

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